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Comparatively Speaking: Silicon Dioxide, Silicon and Silicone

Contact Author Anthony J. O'Lenick, Jr., Siltech LLC and IFSCC Education Chair
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What's in a name? In this case, major differences in chemistry and form.

A great deal of interest has recently been expressed over the chemistry and terminology used in the preparation of silicones, especially as replacements for D4 and D5 are sought. As such, this column aims to provide an understanding of the relationships between these raw materials and the silicones found in personal care.

Silicon Dioxide

Silicon dioxide is SiO2, also is known as silica, silicic acid or silicic acid anhydride. Its name is derived from the Latin Silex. The CAS number for silicon dioxide is 7631-86-9, and the most common form of silicon dioxide is quartz. Quartz makes up more than 10% of the Earth’s crust; it is also a major component of sand. It is estimated that 95% of commercial silicon dioxide is used in the construction industry to make portland cement, though another use is for making glass—hydrated silica is even used in toothpaste to remove plaque.

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Silicon dioxide is also the starting point for making silicone polymers, although the process for making them is equipment-intensive and produces a number of different materials. As such, finding commercial uses for each intermediate in the process is necessary in order to run the plant in a cost-effective manner. The few plants that actually start with the silicon element, described next, and process it all the way through to silicone polymers are called crushers; there are only a handful of companies in this group.

Silicon

Silicon is element 14 on the periodic chart (see Figure 1). While it is an abundant material, it rarely is found in its elemental form.

Figure 1. Elemental silicon

CT1808-OLenick-Fig1-Silicon

Silicon can also be made by the reaction of silicon dioxide and a source of carbon. This reaction, shown in Figure 2, requires a high temperature, and produces CO2 and a product with a melting point of 1,414°C:

Figure 2. Synthesis of silicon

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The conversion of quartz to silicon is an amazing transformation. Figure 3 shows the starting quartz in the upper left and the resulting silicon in the lower right.

Figure 3. Starting quartz and final silicon

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The resultant silicon—without an e on the end—is ground into a fine powder and reacted with methyl chloride to make chloro-silanes via the Rochow Process. This reaction is shown in Figure 4:

Figure 4. The Rochow Process

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Chlorosilanes are then hydrolyzed by the addition of water, resulting in a liberation of HCl and a variety of species known as hydrolysates. The hydrosylates are then fractionated to yield the raw materials needed to make silicone polymers. Silanes as a group have only one Si in their molecule. Octyl trimethoxy silane is one example, shown in Figure 5:

Figure 5. Example silane

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Silicone

The term silicone, also called polysiloxane, describes a group of polymers that have repeating groups, as depicted in Figure 6.

Figure 6. Silicone or polysiloxane structure

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The simplest polydimethylsiloxanes are fluids, which are sold by viscosity. Figure 7 shows the most common-viscosity silicone fluid sold, and the approximate non-blended molecular weight.

Figure 7. Example polydimethylsiloxane

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The molecular weight to viscosity relationship is shown in Table 1:

 Table 1. Molecular weight to viscosity relationship of silicones

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Organo-functional materials are made by a process called hydrosilylation. This process reacts alpha unsaturation with silanic hydrogen (Si-H) to make a new Si-(CH2)3-R product.

Reference

AJ O’Lenick, Jr, Silicones for Personal Care, 2nd edn, available at http://www.scientificspectator.com/documents/book%20service/Anthony%20O'Lenick%20Silicones%20for%20Personal%20Care.pdf (Accessed Aug 27, 2018)

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