Thickening Toothpaste Formulations

February 17, 2009 | Contact Author | By: Roger E. Stier, Ph.D., Noville, Inc.
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  • Article
  • Keywords/Abstract

Keywords: rheology | pseudoplasticity | thixotropy | binder | lean solvent system

Abstract: The combined knowledge of rheology and chemistry of binders together with the art of proper formulation leads to the production of aesthetically pleasing dentifrice formulations.

One aspect of formulating a dentifrice is the role that thickeners and binders play in a dentifrice formula and how the selection of these materials produces different end results. This article discusses the different thickeners used in toothpaste formulations and explains rheological theory that serves as a strong guide to formulators in achieving predictable outcomes.

Rheology, according to a dictionary definition, is “the science dealing with the deformation and flow of matter.” In this article, rheology is always a result of the application of direct force.

Viscosity is the measure of fluid friction, which is internal friction produced when one layer of fluid is caused to move in relationship to another layer of fluid. A highly viscous material is one possessing a great deal of internal friction; it will not pour or spread as easily as material of lesser viscosity.

 Newtonian systems: A simplified explanation of the basic theory of viscosity was set forth by Newton. He described a material containing two parallel planes of fluid of equal area “A” separated by a distance “dx” and moving in the same direction at velocities “V1” and “V2,” where the difference of these velocities is “dv,” which is also called the velocity gradient. According to Newton, the force “F” required to sustain this velocity difference is proportional to the velocity difference and can be expressed as follows: F/A = h(dv/dx) where “h” is a constant for a given material and is termed the material’s viscosity.