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Ingredient Profile: Distearyldimethylammonium Chloride

By: Mike Fevola, Johnson & Johnson
Posted: February 3, 2011, from the February 2011 issue of Cosmetics & Toiletries.

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O/W emulsions comprising DSDMAC can be prepared by either “one-pot” or two-phase processes. In the one-pot process, the emulsion is formed by dispersing the DSDMAC, fatty alcohols, specified emollients, and glycerin in water at 82–87°C with sufficient agitation to form a homogeneous mixture, which is then cooled by adding additional water with increasing agitation.9 The two-phase process involves heating an oil phase comprising DSDMAC, fatty alcohols and specified emollients to 75–80 °C, then dispersing it into an aqueous phase comprising water and humectants, e.g. glycerin, at the same temperature. Once formed, the o/w emulsion is homogenized until uniform and cooled under gentle stirring.10

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References
Send e-mail to CT_author@allured.com.
1. Distearyldimonium Chloride, Monograph ID 935, in the International Cosmetic Ingredient Dictionary and Handbook, 13th edn, Personal Care Products Council: Washington, USA (2010)
2. WM Linfield, Straight-chain alkyl ammonium compounds, ch 2 in Cationic Surfactants, Surfactant Science Series, vol. 4, E Jungermann, ed, Marcel Dekker, New York (1970) pp 9–70
3. K Visek, Amines, fatty, in Kirk-Othmer Encyclopedia of Chemical Technology, published online, John Wiley and Sons, Hoboken, NJ USA (Aug 15, 2003) pp 518–537
4. M Dery, Quaternary ammonium compounds, in Kirk-Othmer Encyclopedia of Chemical Technology, published online, John Wiley and Sons, Hoboken, NJ USA (Dec 4, 2000) pp 1–24
5. RG Laughlin, RL Munyon, YC Fu and AJ Fehl, Physical science of the dioctadecyldimethylammonium chloride-water system. 1. Equilibrium phase behavior, J Phys Chem 94 6 2546–2552 (1990)
6. R Nagarajan, Molecular packing parameter and surfactant self-assembly: The neglected role of the surfactant tail, Langmuir 18 1 31–38 (2002)
7. RG Laughlin, RL Munyon, JL Burns, TW Coffindaffer and Y Talmon, Physical science of the dioctadecyldimethylammonium chloride-water system. 3. Colloidal aspects, J Phys Chem 96 1 343–383 (1992)
8. US 2950255A, Detergent composition, SR Goff, assigned to The Gillette Co. (Aug 23, 1960)
9. US 4389418, Skin care composition, CK Burton, assigned to SC Johnson and Son, Inc. (Jun 21, 1983)
10. Varisoft TA 100 Product Bulletin, Evonik Goldschmidt GmbH: Essen, Germany (Sep 2009)